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RedoxElectrolysisCritA_May2020

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Last updated over 5 years ago
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QUESTIONS (levels adjusted for an open book test)
Strand i. describe scientific knowledge
Question 1
1.

Identify the row with both correct statements for the following electrochemical processes:
[Level 1-2]




Question 2
2.

Water in swimming pools can be purified using a chlorinating cell, where an aqueous solution of sodium chloride is electrolysed to produce chlorine. Identify the products formed at the anode and cathode.
[Level 5-6]

Question 3
3.

In a voltaic cell the redox reactions occur spontaneously. Which statement(s) accurately describe the processes of a voltaic cell? [Level 1-2]

Question 4
4.

In the electrolysis of molten sodium chloride, sodium ions: [Level 5-6]

Question 5
5.

The reactivity series lists metals in order of reactivity. The most easily oxidised metals can be found
[Level 3-4]

Question 6
6.

Which of the following equations represents the reduction of a metal? [Level 3-4]

For the following half-equations (a and b)
a) Cu(s) → Cu2+(aq) + 2e-
b) Ag+(aq) + e- → Ag(s)
Question 7
7.

i. Identify which is oxidation and which is reduction. [Level 1-2]

Question 8
8.

ii. Combine the half-equations to form a balanced redox equation. [Level 7-8]

Strand ii apply scientific knowledge and understanding to solve problems set in familiar and unfamiliar situations
A student performed the electrolysis of molten lead (II) bromide (PbBr2) using the apparatus show.

henniscience.weebly.com

The student made a number of observations
  • The light bulb did not light up straight away
  • Brown gas was observed at the positive electrode
  • Molten metal was observed at the negative electrode.
Question 9
9.

i. Explain why the bulb did not initially light up. [level 7-8]

Question 10
10.

ii. Write the half-equation for the reaction taking place at the positive electrode [level 5-6]

Question 11
11.

iii. Write the half-equation for the reaction taking place at the negative electrode [level 5-6]

Question 12
12.

iv. Explain why lead is formed at the negative electrode and why this reaction taking place at the negative electrode is viewed as a reduction reaction?
[level 7-8]

The diagram shows a voltaic cell:

Source: Harwood, Richard, and Ian Lodge. Cambridge IGCSE Chemistry Coursebook. Cambridge University Press, 2014.
Question 13
13.

i. State and explain the direction of electron flow in the external circuit. [level 3-4]

Question 14
14.

ii. State and explain whether oxidation or reduction occurs at each electrode. [level 5-6]

Question 15
15.

iii. State which electrode is the cathode and which is the anode. [level 3-4]

Question 16
16.

iv. Explain the function of the salt bridge. [level 7-8]

Question 17
17.

v. Explain whether the voltage will increase or decrease when the nickel half-cell is replaced by a Cu/Cu2+ half-cell. [level 7-8]

iii. analyse information to make scientifically supported judgments.
A student added different metals to solutions of metal ions and recorded the observations

Question 18
18.

i. Identify what is the most reactive metal [level 1-2]

Question 19
19.

ii. Identify what is the least reactive metal [level 1-2]

Question 20
20.

iii. For the metals tested, write a reactivity series, starting with the most reactive.
[level 3-4]

Question 21
21.

iv. With the aid of chemical reactions (half equations and overall balanced equation), explain the observations for the reaction of magnesium with copper sulphate. [level 7-8]

Aluminium metal can be obtained from the redox reaction between aluminium oxide (alumina) and solid carbon. The product of this redox reaction is carbon dioxide.
Question 22
22.

i. Write down a balanced equation for the redox reaction between aluminium oxide and carbon. [level 5-6]

Question 23
23.

ii. Identify the element that is oxidized and the element that is reduced. Justify your answers. [level 7-8]

Using a simple voltaic cell, as shown, a student carried out an experiment to investigate the order of reactivity of tin, nickel and iron.

The following results were obtained:

Question 24
24.

i. Explain why the student decided to have copper as metal X in each experiment?
[level 3-4]

Question 25
25.

ii. List these metals in order of reactivity (most reactive first). [level 3-4]