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01.27.21 - Physical Properties and IMAFs

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Physical Properties and Intermolecular Forces


Objectives
Students will:
  • predict the type of intermolecular attractive force that will form between two identical particles.
  • explain the differences in melting or boiling points based on the types of intermolecular forces present between particles.
Why?
So why do we care about intermolecular attractive forces? Think about water molecules. When an ice cube melts or when water boils in a pan on the stove, the covalent bonds holding the hydrogen and oxygen atoms together in the molecule remain intact. However, the attractions between water molecules, the intermolecular attractions, are affected by melting and boiling. Intermolecular attractions influence a variety of physical properties of compounds including melting points, boiling points, and solubility (ability to dissolve). In the last activity, you investigated the types of intermolecular attractive forces that cause molecules to attract. In this activity, you will investigate how these intermolecular attractive forces determine the melting point, boiling point, and solubility of a substance.
This interactive let's you change the intermolecular attractions between particles at the same temperature. While you can't actually do this in real life, this simulation will help you explore how the strength of intermolecular attractions determine if a substance is a solid, liquid, or gas at a given temperature.

Use this interactive to answer questions 1-4

Question 1
1.

Question 2
2.

Question 3
3.

Question 4
4.

Part 1 - Melting and Boiling Points
The boiling point of a substance is the temperature at which the substance changes states from liquid to gas. Boiling point is a physical property that is determined by intermolecular attractions. In the interactive below, there are two tiny drops of liquid, one polar and the other non-polar. Use the interactive to answer questions 5-8

Question 5
5.

Question 6
6.

Question 7
7.

Question 8
8.

The diagram below shows two types of molecules that contain carbon atoms. In each molecule, carbon atoms are gray, hydrogen atoms are white, and oxygen atoms are red.

Use the diagram below to answer questions 9-14.
Question 9
9.

Question 10
10.

Question 11
11.

Question 12
12.

Return to the main Google meet.
Part 2 - Solubility
You probably know that oil and water don't mix. Did you ever wonder why? The interactive below shows polar water molecules and nonpolar oil molecules in a container together. Use the key below to identify each type of molecule.


Use the button to "shake up" the oil and water mixture. Then watch to see what happens to the oil and water as you let the container "settle".

Question 13
13.

Question 14
14.

Question 15
15.

Using what you know of intermolecular attractions, why don't oil and water mix?

Question 16
16.

Part 3 - IMAFs and COVID
IMAFs play a huge role in something that we do multiple times every single day: washing our hands.

Watch the video below about surfactants, then answer questions 17-18.

Question 17
17.

Question 18
18.

Draggable itemarrow_right_altCorresponding Item
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Watch the video below about how soap interacts with the coronavirus. As you watch, consider what you learned about IMAFs in substances such as water, oil, and alcohol..


Answer questions 19-
Question 19
19.

Question 20
20.

Question 21
21.

Question 22
22.

Extension Questions

The following set of questions is an optional activity for studens who are curious about salts and sugars in water
Click on the link below to launch a simulation to show how salt and sugar dissolve in water. Note: This simulation won't run on an iPad or some tablets. If someone in your group can't open the simulation, please have someone in the group share their screen so all team members can see the simulation.

https://phet.colorado.edu/sims/cheerpj/sugar-and-salt-solutions/latest/sugar-and-salt-solutions.html?simulation=sugar-and-salt-solutions
Question 24
24.

Question 25
25.

Question 26
26.

Spend a few minutes interacting with the simulation. Make sure to look at all three screens (Macro, Micro, and Water). Then write down three observations.

Question 27
27.

Question 28
28.

Which statement best describes a substance that has weak intermolecular attractive forces between particles?
The particles don't move much and are spread out.
The particles move freely and are close together.
The particles move freely and are spread out.
The particles don't move much and are close together.
Which statement best describes a substance that has strong intermolecular attractive forces between particles?
The particles don't move much and are spread out.
The particles move freely and are spread out.
The particles don't move much and are close together.
The particles move freely and are close together.
Identify the state of matter for the substance with weak intermolecular attractions.
liquid
gas
solid
Identify the state of matter for the substance with strong intermolecular attractions.
solid
gas
liquid
Which liquid has the lowest boiling point?
The nonpolar liquid
Both liquids boiled at the same time.
The polar liquid
When a liquid boils, what is broken or disrupted?
covalent bonds
intermolecular attractions
molecules
ions
Which substance has stronger intermolecular attractions?
The polar liquid
The nonpolar liquid
Both liquids have the same intermolecular attractive forces.
How do intermolecular attractions affect the boiling point of a substance?
The stronger the intermolecular attractions, the higher the boiling point.
The weaker the intermolecular attractions, the higher the boiling point.
Intermolecular attractions don't affect boiling points.
What is different about the structure of hydrocarbon molecules and alcohol molecules?
Hydrocarbons are made up of only carbon and hydrogen atoms, but alcohols also contain oxygen atoms.
Alcohols are made up of only carbon and hydrogen atoms, but hydrocarbons also contain oxygen atoms.
Hydrocarbons are bigger molecules than alcohols.
Alcohols are smaller molecules than hydrocarbons.
Classify the molecules as polar or nonpolar.
hydrocarbon
alcohol
Polar molecule
Nonpolar molecule
Identify the type of intermolecular forces present between each molecule listed.
hydrocarbon
alcohol
London dispersion forces
dipole-dipole attractions
hydrogen bonds
ion-ion attractions
Which compound would have a higher melting point, methane, CH4, or methanol, CH3OH? Why?
Methane would have a higher melting point because its intermolecular attractions are weaker.
Methanol would have a higher melting point because it is a bigger molecule.
Methane would have a higher melting point because it is a smaller molecule.
Methanol would have a higher melting point because its intermolecular attractions are stronger.
What types of intermolecular attractions are found between water molecules?
dipole-dipole attractions
hydrogen bonds
ion-ion attractions
London disperion forces
What types of intermolecular attractions are found between oil molecules?
London disperion forces
hydrogen bonds
ion-ion attractions
dipole-dipole attractions
Identify the combination of substances that will mix or dissolve. Select all that apply.
Nonpolar liquid in another nonpolar liquid
Polar liquids in nonpolar liquids
Ionic solid in polar liquid
Polar liquid in another polar liquid
Ionic solid in nonpolar liquid
According to the video, what is another term for "surfactant"?
a macroscopic analogy
candy corn
soap
Match the phrase below with the best term.
"water hating"
hydrophilic
"water loving"
hydrophobic
The model from the video shown below is describing the general structure of a soap molecule.


Categorize the following characteristics with the different ends of a soap molecule (a and b)
hydrophobic end
attracted to water
hydrophilic end
nonpolar end
polar end
attracted to fats (oils)
a
b
Whaich of the following best describes what soap does to the coronavirus?
The hydrophobic end of soap tears apart the fatty layer around the virus
The hydrophilic end of soap extracts water from the inside of the virus
The hydrophilic end of soap tears apart the fatty layer around the virus
The hydrophobic end of soap extracts water from the inside of the virus
The video claims that alcohol based hand sanitizers work similarly to soap in destroying the coronavirus.

Consider what you learned about alcohols in the activity above. What is the property of soap and alcohol molecules that makes them effective at "exploding" the coronavirus? (Hint: It may help to revisit the picture above #9)
both alcohol and soap molecules have a polar end
both alcohol and soap have low melting points
both alcohol and soap are made of hydrocarbons
Hand sanitizer is always effective at killing the coronavirus.

(Optional: Check out the How do Hand Sanitizers Work video from American Chemical Society)
True
False
What happens to salt or sodium chloride, NaCl, when it dissolves in water?
One sodium ion and one chloride ion stay together and get surrounded by water molecules.
The sodium and chloride ions stay together and the whole group of ions get surrounded by water.
The sodium ions and chloride separate and get surrounded by water molecules.
What happens to sugar, C12H22O11, when it dissolves in water?
Individual sugar molecules stay together and get surrounded by water molecules.
The carbon, hydrogen, and oxygen atoms separate and get surrounded by water molecules.
A group of sugar molecules stay together and the whole group gets surrounded by water.
What types of intermolecular attractions are found between particles NaCl?
hydrogen bonds
London disperion forces
dipole-dipole attractions
ion-ion attractions
What types of intermolecular attractions are found between sugar molecules?
hydrogen bonds
ion-ion attractions
dipole-dipole attractions
London disperion forces