Redox Practical Investigation

Last updated 10 months ago
16 questions

REDOX PRACTICAL INVESTIGATION [90 MARKS]

I have made and inserted gifs of the simulations for you, which you into this Formative.
The simulation in this investigation can be accessed at:
http://intro.chem.okstate.edu/1515F01/Laboratory/ActivityofMetals/home.html

Part A: Reactivity series

Some metals react readily with others, displacing them out of a solution and sometimes, there is no reaction. In this simulation you need to observe in each case whether a reaction takes place between the two metals. Where a reaction does take place, describe your observations. You will also calculate the Eo cell value for each combination. [If the gifs in this section don't work, use this link to access a video: https://drive.google.com/open?id=1Wj9jd-HvyKbvzOMqjYe6fOkCOCwmx15x ]

Simulation 1

The reactions of Mg with various metal solutions

8

Use the simulation to observe the reactivity of magnesium in each solution. FOR EACH BEAKER, FIRST record if a reaction takes place or does not take place. SECOND If a reaction takes place, record ALL your observations by choosing from the list of options. If there is no obvious change to the colour of a solution or the piece of metal, then no observation about the solution or piece of metal needs to be made.

  • No reaction takes place
  • Reaction takes place
  • Observation: A dark grey deposit forms on the metal
  • Observation: A silvery grey deposit forms on the metal
  • Observation: A reddish-brown deposit forms on the metal
  • Observation: The blue solution becomes lighter in colour
  • Observation: The blue solution becomes darker in colour
  • Observation: The colourless solution turns blue
  • Mg in Mg(NO3)2
  • Mg in Zn(NO3)2
  • Mg in Cu(NO3)2
  • Mg in AgNO3
4

TWO observations were seen in the Mg in Cu(NO3)2 experiment. Explain why each one occured.

8

Calculate the Eo cell values for each of the redox reactions with magnesium metal. Choose the correct answer (with the correct sign) for each combination from the list of options.

  • - 3,17 V
  • - 2,71 V
  • - 1,61 V
  • - 1,56 V
  • - 1,10 V
  • - 0,46 V
  • 0,00 V
  • + 0,46 V
  • + 1,10 V
  • + 1,56 V
  • + 1,61 V
  • + 2,71 V
  • + 3.17 V
  • Mg in Mg(NO3)2
  • Mg in Zn(NO3)2
  • Mg in AgNO3
  • Mg in Cu(NO3)2

Simulation 2

The reactions of Cu with various metal solutions


8

Use the simulation to observe the reactivity of copper in each solution. FOR EACH BEAKER, FIRST record if a reaction takes place or does not take place. SECOND If a reaction takes place, record ALL your observations by choosing from the list of options. If there is no obvious change to the colour of a solution or the piece of metal, then no observation about the solution or piece of metal needs to be made.

  • No reaction takes place
  • Reaction takes place
  • Observation: A dark grey deposit forms on the metal
  • Observation: A silvery grey deposit forms on the metal
  • Observation: A reddish-brown deposit forms on the metal
  • Observation: The blue solution becomes lighter in colour
  • Observation: The blue solution becomes darker in colour
  • Observation: The colourless solution turns blue
  • Cu in Mg(NO3)2
  • Cu in Zn(NO3)2
  • Cu in Cu(NO3)2
  • Cu in AgNO3
8

Calculate the Eo cell values for each of the redox reactions with copper metal. Choose the correct answer (with the correct sign) for each combination from the list of options.

  • - 3,17 V
  • - 2,71 V
  • - 1,61 V
  • - 1,56 V
  • - 1,10 V
  • - 0,46 V
  • 0,00 V
  • + 0,46 V
  • + 1,10 V
  • + 1,56 V
  • + 1,61 V
  • + 2,71 V
  • + 3.17 V
  • Cu in Mg(NO3)2
  • Cu in Zn(NO3)2
  • Cu in Cu(NO3)2
  • Cu in AgNO3

Simulation 3

The reactions of Zn with various metal solutions

8

Use the simulation to observe the reactivity of zinc in each solution. FOR EACH BEAKER, FIRST record if a reaction takes place or does not take place. SECOND If a reaction takes place, record ALL your observations by choosing from the list of options. If there is no obvious change to the colour of a solution or the piece of metal, then no observation about the solution or piece of metal needs to be made.

  • No reaction takes place
  • Reaction takes place
  • Observation: A dark grey deposit forms on the metal
  • Observation: A silvery grey deposit forms on the metal
  • Observation: A reddish-brown deposit forms on the metal
  • Observation: The blue solution becomes lighter in colour
  • Observation: The blue solution becomes darker in colour
  • Observation: The colourless solution turns blue
  • Zn in Mg(NO3)2
  • Zn in Zn(NO3)2
  • Zn in Cu(NO3)2
  • Zn in AgNO3
8

Calculate the Eo cell values for each of the redox reactions with zinc metal. Choose the correct answer (with the correct sign) for each combination from the list of options.

  • - 3,17 V
  • - 2,71 V
  • - 1,61 V
  • - 1,56 V
  • - 1,10 V
  • - 0,46 V
  • 0,00 V
  • + 0,46 V
  • + 1,10 V
  • + 1,56 V
  • + 1,61 V
  • + 2,71 V
  • + 3.17 V
  • Zn in Mg(NO3)2
  • Zn in Zn(NO3)2
  • Zn in Cu(NO3)2
  • Zn in AgNO3

Simulation 4

The reactions of Ag with various metal solutions

8

Use the simulation to observe the reactivity of silver in each solution. FOR EACH BEAKER, FIRST record if a reaction takes place or does not take place. SECOND If a reaction takes place, record ALL your observations by choosing from the list of options. If there is no obvious change to the colour of a solution or the piece of metal, then no observation about the solution or piece of metal needs to be made.

  • No reaction takes place
  • Reaction takes place
  • Observation: A dark grey deposit forms on the metal
  • Observation: A silvery grey deposit forms on the metal
  • Observation: A reddish-brown deposit forms on the metal
  • Observation: The blue solution becomes lighter in colour
  • Observation: The blue solution becomes darker in colour
  • Observation: The colourless solution turns blue
  • Ag in Mg(NO3)2
  • Ag in Zn(NO3)2
  • Ag in Cu(NO3)2
  • Ag in AgNO3
8

Calculate the Eo cell values for each of the redox reactions with silver metal. Choose the correct answer (with the correct sign) for each combination from the list of options.

  • - 3,17 V
  • - 2,71 V
  • - 1,61 V
  • - 1,56 V
  • - 1,10 V
  • - 0,46 V
  • 0,00 V
  • + 0,46 V
  • + 1,10 V
  • + 1,56 V
  • + 1,61 V
  • + 2,71 V
  • + 3.17 V
  • Ag in Mg(NO3)2
  • Ag in Zn(NO3)2
  • Ag in Cu(NO3)2
  • Ag in AgNO3
2

Conclusion:

Based on the results of Part A of this investigation, rank the metals in order from most reactive to least reactive:

  1. Ag
  2. Zn
  3. Mg
  4. Cu

Part B: Redox at the molecular level

In this simulation you can observe a redox reaction at the molecular level. [If the gifs in this section don't work, use this link to access a video: https://drive.google.com/open?id=1lfOSDtnb-MZP1KXgGOL8uQvwrbvoJnDi ]

Simulation 5

Zn in Cu(NO3)2 at the molecular level

4

Identify the half-reactions for this reaction:

  • Cu2+ + 2e- ➝ Cu
  • Cu ➝ Cu2+ + 2e-
  • Zn2+ + 2e- ➝ Zn
  • Zn ➝ Zn2+ + 2e-
  • Oxidation 1/2 reaction:
  • Reduction 1/2 reaction:
1

Is this reaction spontaneous or non-spontaneous?

5

Explain your answer above by refering to the relative strengths of the reducing agents. Complete the explanation by dragging the appropriate substance into each step of the explanation:

  • Zn
  • Zn2+
  • Cu
  • Cu2+
  • _____ is a better reducing agent
  • than _______
  • Therefore in the presence of _____ ,
  • _______ will/will not [don't need to distinguish]
  • be readily reduced to form ________

Simulation 6

Cu in Zn(NO3)2 at the molecular level

4

Identify the half-reactions for this reaction:

  • Cu2+ + 2e- ➝ Cu
  • Cu ➝ Cu2+ + 2e-
  • Zn2+ + 2e- ➝ Zn
  • Zn ➝ Zn2+ + 2e-
  • Oxidation 1/2 reaction:
  • Reduction 1/2 reaction:
1

Is this reaction spontaneous or non-spontaneous?

5

Explain your answer above by refering to the relative strengths of the reducing agents. Complete the explanation by dragging the appropriate substance into each step of the explanation:

  • Zn
  • Zn2+
  • Cu
  • Cu2+
  • _____ is a better reducing agent
  • than _______
  • Therefore in the presence of _____ ,
  • _______ will/will not [don't need to distinguish]
  • be readily reduced to form ________