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Double Science (Chemistry) Retrospective Revision guide

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Last updated over 1 year ago
130 questions
Note from the author:
1 Principles of chemistry
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2 Inorganic chemistry
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3 Physical chemistry
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4 Organic chemistry
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The iGCSE Edexcel Double Award Science (Chemistry) syllabus for students to RAG rate to aid with revision

(a) States of matter

Question 1
1.

Question 2
2.

Question 3
3.

Question 4
4.

(b) Elements, compounds and mixtures

Question 5
5.

Question 6
6.

Question 7
7.

Question 8
8.

Question 9
9.

Question 10
10.

(c) Atomic structure

Question 11
11.

Question 12
12.

Question 13
13.

Question 14
14.

(d) The Periodic Table

Question 15
15.

Question 16
16.

Question 17
17.

Question 18
18.

Question 19
19.

Question 20
20.

Question 21
21.

(e) Chemical formulae, equations and calculations

Question 22
22.

Question 23
23.

Question 24
24.

Question 25
25.

Question 26
26.

Question 27
27.

Question 28
28.

Question 29
29.

Question 30
30.

Question 31
31.

(f) Ionic bonding

Question 32
32.

Question 33
33.

Question 34
34.

Question 35
35.

Question 36
36.

Question 37
37.

Question 38
38.

(g) Covalent bonding

Question 39
39.

Question 40
40.

Question 41
41.

Question 42
42.

Question 43
43.

Question 44
44.

Question 45
45.

Question 46
46.

(a) Group 1 (alkali metals) – lithium, sodium and potassium

Question 47
47.

Question 48
48.

Question 49
49.

(b) Group 7 (halogens) – chlorine, bromine and iodine

Question 50
50.

Question 51
51.

Question 52
52.

(c) Gases in the atmosphere

Question 53
53.

Question 54
54.

Question 55
55.

Question 56
56.

Question 57
57.

Question 58
58.

(d) Reactivity series

Question 59
59.

Question 60
60.

Question 61
61.

Question 62
62.

Question 63
63.

Question 64
64.

Question 65
65.

(e) Acids, alkalis and titrations

Question 66
66.

Question 67
67.

Question 68
68.

Question 69
69.

Question 70
70.

f) Acids, bases and salt preparations

Question 71
71.

Question 72
72.

Question 73
73.

Question 74
74.

Question 75
75.

Question 76
76.

Question 77
77.

(g) Chemical tests

Question 78
78.

Question 79
79.

Question 80
80.

Question 81
81.

Question 82
82.

Question 83
83.

Question 84
84.

(a) Energetics

Question 85
85.

Question 86
86.

Question 87
87.

Question 88
88.

Question 89
89.

(b) Rates of reaction

Question 90
90.

Question 91
91.

Question 92
92.

Question 93
93.

Question 94
94.

Question 95
95.

Question 96
96.

(c) Reversible reactions and equilibria

Question 97
97.

Question 98
98.

(a) Introduction

Question 99
99.

Question 100
100.

Question 101
101.

Question 102
102.

Question 103
103.

Question 104
104.

(b) Crude oil

Question 105
105.

Question 106
106.

Question 107
107.

Question 108
108.

Question 109
109.

Question 110
110.

Question 111
111.

Question 112
112.

Question 113
113.

Question 114
114.

Question 115
115.

Question 116
116.

(c) Alkanes

Question 117
117.

Question 118
118.

Question 119
119.

Question 120
120.

(d) Alkenes

Question 121
121.

Question 122
122.

Question 123
123.

Question 124
124.

Question 125
125.

Question 126
126.

(e) Synthetic polymers

Question 127
127.

Question 128
128.

Question 129
129.

Question 130
130.

1.1
understand the three states of matter in terms of the arrangement, movement and
energy of the particles
I know none of this
I know some of this
I am confident in this
1.2
understand the interconversions between the three states of matter in terms of:
• the names of the interconversions
• how they are achieved
• the changes in arrangement, movement and energy of the particles.
I know none of this
I know some of this
I am confident in this
1.3
understand how the results of experiments involving the dilution of coloured solutions
and diffusion of gases can be explained
I know none of this
I know some of this
I am confident in this
1.4
know what is meant by the terms:
• solvent
• solute
• solution
• saturated solution.
I know none of this
I know some of this
I am confident in this
1.8
understand how to classify a substance as an element, compound or mixture
I know none of this
I know some of this
I am confident in this
1.9
understand that a pure substance has a fixed melting and boiling point, but that a
mixture may melt or boil over a range of temperatures
I know none of this
I know some of this
I am confident in this
1.10
describe these experimental techniques for the separation of mixtures:
• simple distillation
• fractional distillation
• filtration
• crystallisation
• paper chromatography.
I know none of this
I know some of this
I am confident in this
1.11
understand how a chromatogram provides information about the composition of a
mixture
I know none of this
I know some of this
I am confident in this
1.12
understand how to use the calculation of Rf values to identify the components of a
mixture
I know none of this
I know some of this
I am confident in this
1.13
practical: investigate paper chromatography using inks/food colourings
I know none of this
I know some of this
I am confident in this
1.14
know what is meant by the terms atom and molecule
I know none of this
I know some of this
I am confident in this
1.15
know the structure of an atom in terms of the positions, relative masses and relative
charges of sub-atomic particles
I know none of this
I know some of this
I am confident in this
1.16
know what is meant by the terms atomic number, mass number, isotopes and relative
atomic mass (Ar)
I know none of this
I know some of this
I am confident in this
1.17
be able to calculate the relative atomic mass of an element (Ar) from isotopic
abundances
I know none of this
I know some of this
I am confident in this
1.18
understand how elements are arranged in the Periodic Table:
• in order of atomic number
• in groups and periods.
I know none of this
I know some of this
I am confident in this
1.19
understand how to deduce the electronic configurations of the first 20 elements from
their positions in the Periodic Table
I know none of this
I know some of this
I am confident in this
1.20
understand how to use electrical conductivity and the acid-base character of oxides to
classify elements as metals or non-metals
I know none of this
I know some of this
I am confident in this
1.21
identify an element as a metal or a non-metal according to its position in the Periodic
Table
I know none of this
I know some of this
I am confident in this
1.22
understand how the electronic configuration of a main group element is related to its
position in the Periodic Table
I know none of this
I know some of this
I am confident in this
1.23
understand why elements in the same group of the Periodic Table have similar
chemical properties
I know none of this
I know some of this
I am confident in this
1.24
understand why the noble gases (Group 0) do not readily react
I know none of this
I know some of this
I am confident in this
1.25
write word equations and balanced chemical equations (including state symbols):
• for reactions studied in this specification
• for unfamiliar reactions where suitable information is provided
I know none of this
I know some of this
I am confident in this
1.26
calculate relative formula masses (including relative molecular masses) (Mr) from
relative atomic masses (Ar)
I know none of this
I know some of this
I am confident in this
1.27
know that the mole (mol) is the unit for the amount of a substance
I know none of this
I know some of this
I am confident in this
1.28
understand how to carry out calculations involving amount of substance, relative
atomic mass (Ar) and relative formula mass (Mr)
I know none of this
I know some of this
I am confident in this
1.29
calculate reacting masses using experimental data and chemical equations
I know none of this
I know some of this
I am confident in this
1.30
calculate percentage yield
I know none of this
I know some of this
I am confident in this
1.31
understand how the formulae of simple compounds can be obtained experimentally,
including metal oxides, water and salts containing water of crystallisation
I know none of this
I know some of this
I am confident in this
1.32
know what is meant by the terms empirical formula and molecular formula
I know none of this
I know some of this
I am confident in this
1.33
calculate empirical and molecular formulae from experimental data
I know none of this
I know some of this
I am confident in this
1.36
practical: know how to determine the formula of a metal oxide by combustion
(e.g. magnesium oxide) or by reduction (e.g. copper(II) oxide)
I know none of this
I know some of this
I am confident in this
1.37
understand how ions are formed by electron loss or gain
I know none of this
I know some of this
I am confident in this
1.38 know the charges of these ions:
• metals in Groups 1, 2 and 3
• non-metals in Groups 5, 6 and 7
• Ag+, Cu2+, Fe2+, Fe3+, Pb2+, Zn2+
• hydrogen (H+), hydroxide (OH–), ammonium (NH4+), carbonate (CO32–), nitrate
(NO3-), sulfate (SO42–).
I know none of this
I know some of this
I am confident in this
1.39
write formulae for compounds formed between the ions listed above
I know none of this
I know some of this
I am confident in this
1.40
draw dot-and-cross diagrams to show the formation of ionic compounds by electron
transfer, limited to combinations of elements from Groups 1, 2, 3 and 5, 6, 7
only outer electrons need be shown
I know none of this
I know some of this
I am confident in this
1.41
understand ionic bonding in terms of electrostatic attractions
I know none of this
I know some of this
I am confident in this
1.42
understand why compounds with giant ionic lattices have high melting and boiling points
I know none of this
I know some of this
I am confident in this
1.43
know that ionic compounds do not conduct electricity when solid, but do conduct
electricity when molten and in aqueous solution
I know none of this
I know some of this
I am confident in this
1.44
know that a covalent bond is formed between atoms by the sharing of a pair of
electrons
I know none of this
I know some of this
I am confident in this
1.45
understand covalent bonds in terms of electrostatic attractions
I know none of this
I know some of this
I am confident in this
1.46
understand how to use dot-and-cross diagrams to represent covalent bonds in:
• diatomic molecules, including hydrogen, oxygen, nitrogen, halogens and hydrogen
halides
• inorganic molecules including water, ammonia and carbon dioxide
• organic molecules containing up to two carbon atoms, including methane, ethane,
ethene and those containing halogen atoms.
I know none of this
I know some of this
I am confident in this
1.47
explain why substances with a simple molecular structures are gases or liquids, or
solids with low melting and boiling points
the term intermolecular forces of attraction can be used to represent all forces
between molecules
I know none of this
I know some of this
I am confident in this
1.48
explain why the melting and boiling points of substances with simple molecular
structures increase, in general, with increasing relative molecular mass
I know none of this
I know some of this
I am confident in this
1.49
explain why substances with giant covalent structures are solids with high melting and
boiling points
I know none of this
I know some of this
I am confident in this
1.50
explain how the structures of diamond, graphite and C60 fullerene influence their
physical properties, including electrical conductivity and hardness
I know none of this
I know some of this
I am confident in this
1.51
know that covalent compounds do not usually conduct electricity
I know none of this
I know some of this
I am confident in this
2.1
understand how the similarities in the reactions of these elements with water provide
evidence for their recognition as a family of elements
I know none of this
I know some of this
I am confident in this
2.2
understand how the differences between the reactions of these elements with air and
water provide evidence for the trend in reactivity in Group 1
I know none of this
I know some of this
I am confident in this
2.3
use knowledge of trends in Group 1 to predict the properties of other alkali metals
I know none of this
I know some of this
I am confident in this
2.5
know the colours, physical states (at room temperature) and trends in physical
properties of these elements
I know none of this
I know some of this
I am confident in this
2.6
use knowledge of trends in Group 7 to predict the properties of other halogens
I know none of this
I know some of this
I am confident in this
2.7
understand how displacement reactions involving halogens and halides provide
evidence for the trend in reactivity in Group 7
I know none of this
I know some of this
I am confident in this
2.9
know the approximate percentages by volume of the four most abundant gases in dry
air
I know none of this
I know some of this
I am confident in this
2.10
understand how to determine the percentage by volume of oxygen in air using
experiments involving the reactions of metals (e.g. iron) and non-metals
(e.g. phosphorus) with air
I know none of this
I know some of this
I am confident in this
2.11
describe the combustion of elements in oxygen, including magnesium, hydrogen and
sulfur
I know none of this
I know some of this
I am confident in this
2.12
describe the formation of carbon dioxide from the thermal decomposition of metal
carbonates, including copper(II) carbonate
I know none of this
I know some of this
I am confident in this
2.13
know that carbon dioxide is a greenhouse gas and that increasing amounts in the
atmosphere may contribute to climate change
I know none of this
I know some of this
I am confident in this
2.14
practical: determine the approximate percentage by volume of oxygen in air using a
metal or a non-metal
I know none of this
I know some of this
I am confident in this
2.15
understand how metals can be arranged in a reactivity series based on their reactions
with:
• water
• dilute hydrochloric or sulfuric acid.
I know none of this
I know some of this
I am confident in this
2.16
understand how metals can be arranged in a reactivity series based on their
displacement reactions between:
• metals and metal oxides
• metals and aqueous solutions of metal salts.
I know none of this
I know some of this
I am confident in this
2.17
know the order of reactivity of these metals: potassium, sodium, lithium, calcium,
magnesium, aluminium, zinc, iron, copper, silver, gold
I know none of this
I know some of this
I am confident in this
2.18
know the conditions under which iron rusts
I know none of this
I know some of this
I am confident in this
2.19
understand how the rusting of iron may be prevented by:
• barrier methods
• galvanising
• sacrificial protection.
I know none of this
I know some of this
I am confident in this
2.20
the terms:
• oxidation
• reduction
• redox
• oxidising agent
• reducing agent
in terms of gain or loss of oxygen and loss or gain of electrons.
I know none of this
I know some of this
I am confident in this
2.21
practical: investigate reactions between dilute hydrochloric and sulfuric acids and
metals (e.g. magnesium, zinc and iron)
I know none of this
I know some of this
I am confident in this
2.28
describe the use of litmus, phenolphthalein and methyl orange to distinguish between
acidic and alkaline solutions
I know none of this
I know some of this
I am confident in this
2.29
understand how to use the pH scale, from 0–14, can be used to classify solutions as
strongly acidic (0–3), weakly acidic (4–6), neutral (7), weakly alkaline (8–10) and
strongly alkaline (11–14)
I know none of this
I know some of this
I am confident in this
2.30
describe the use of universal indicator to measure the approximate pH value of an
aqueous solution
I know none of this
I know some of this
I am confident in this
2.31
know that acids in aqueous solution are a source of hydrogen ions and alkalis in a
aqueous solution are a source of hydroxide ions
I know none of this
I know some of this
I am confident in this
2.32
know that alkalis can neutralise acids
I know none of this
I know some of this
I am confident in this
2.34
know the general rules for predicting the solubility of ionic compounds in water:
• common sodium, potassium and ammonium compounds are soluble
• all nitrates are soluble
• common chlorides are soluble, except those of silver and lead(II)
• common sulfates are soluble, except for those of barium, calcium and lead(II)
• common carbonates are insoluble, except for those of sodium, potassium and
ammonium
• common hydroxides are insoluble except for those of sodium, potassium and
calcium (calcium hydroxide is slightly soluble).
I know none of this
I know some of this
I am confident in this
2.35
understand acids and bases in terms of proton transfer
I know none of this
I know some of this
I am confident in this
2.36
understand that an acid is a proton donor and a base is a proton acceptor
I know none of this
I know some of this
I am confident in this
2.37
describe the reactions of hydrochloric acid, sulfuric acid and nitric acid with metals,
bases and metal carbonates (excluding the reactions between nitric acid and metals)
to form salts
I know none of this
I know some of this
I am confident in this
2.38
know that metal oxides, metal hydroxides and ammonia can act as bases, and that
alkalis are bases that are soluble in water
I know none of this
I know some of this
I am confident in this
2.39
describe an experiment to prepare a pure, dry sample of a soluble salt, starting from
an insoluble reactant
I know none of this
I know some of this
I am confident in this
2.42
practical: prepare a sample of pure, dry hydrated copper(II) sulfate crystals starting
from copper(II) oxide
I know none of this
I know some of this
I am confident in this
2.44
describe tests for these gases:
• hydrogen
• oxygen
• carbon dioxide
• ammonia
• chlorine.
I know none of this
I know some of this
I am confident in this
2.45
describe how to carry out a flame test
I know none of this
I know some of this
I am confident in this
2.46
know the colours formed in flame tests for these cations:
• Li+ is red
• Na+ is yellow
• K+ is lilac
• Ca2+ is orange-red
• Cu2+ is blue-green.
I know none of this
I know some of this
I am confident in this
2.47
describe tests for these cations:
• NH4+ using sodium hydroxide solution and identifying the gas evolved
• Cu2+, Fe2+ and Fe3+ using sodium hydroxide solution.
I know none of this
I know some of this
I am confident in this
2.48
describe tests for these anions:
• Cl–, Br– and I– using acidified silver nitrate solution
• SO42– using acidified barium chloride solution
• CO32– using hydrochloric acid and identifying the gas evolved.
I know none of this
I know some of this
I am confident in this
2.49
describe a test for the presence of water using anhydrous copper(II) sulfate
I know none of this
I know some of this
I am confident in this
2.50
describe a physical test to show whether a sample of water is pure
I know none of this
I know some of this
I am confident in this
3.1
know that chemical reactions in which heat energy is given out are described as
exothermic, and those in which heat energy is taken in are described as endothermic
I know none of this
I know some of this
I am confident in this
3.2
describe simple calorimetry experiments for reactions such as combustion,
displacement, dissolving and neutralisation
I know none of this
I know some of this
I am confident in this
3.3
calculate the heat energy change from a measured temperature change using the
expression Q = mcΔT
I know none of this
I know some of this
I am confident in this
3.4
calculate the molar enthalpy change (ΔH) from the heat energy change, Q
I know none of this
I know some of this
I am confident in this
3.8
practical: investigate temperature changes accompanying some of the following types
of change:
• salts dissolving in water
• neutralisation reactions
• displacement reactions
• combustion reactions.
I know none of this
I know some of this
I am confident in this
3.9
describe experiments to investigate the effects of changes in surface area of a solid,
concentration of a solution, temperature and the use of a catalyst on the rate of a
reaction
I know none of this
I know some of this
I am confident in this
3.10
describe the effects of changes in surface area of a solid, concentration of a solution,
pressure of a gas, temperature and the use of a catalyst on the rate of a reaction
I know none of this
I know some of this
I am confident in this
3.11
explain the effects of changes in surface area of a solid, concentration of a solution,
pressure of a gas and temperature on the rate of a reaction in terms of particle
collision theory
I know none of this
I know some of this
I am confident in this
3.12
know that a catalyst is a substance that increases the rate of a reaction, but is
chemically unchanged at the end of the reaction
I know none of this
I know some of this
I am confident in this
3.13
know that a catalyst works by providing an alternative pathway with lower activation
energy
I know none of this
I know some of this
I am confident in this
3.15
practical: investigate the effect of changing the surface area of marble chips and of
changing the concentration of hydrochloric acid on the rate of reaction between
marble chips and dilute hydrochloric acid
I know none of this
I know some of this
I am confident in this
3.16
practical: investigate the effect of different solids on the catalytic decomposition of
hydrogen peroxide solution
I know none of this
I know some of this
I am confident in this
3.17
know that some reactions are reversible and this is indicated by the symbol ⇌ in
equations
I know none of this
I know some of this
I am confident in this
3.18
describe reversible reactions such as the dehydration of hydrated copper(II) sulfate
and the effect of heat on ammonium chloride
I know none of this
I know some of this
I am confident in this
4.1
know that a hydrocarbon is a compound of hydrogen and carbon only
I know none of this
I know some of this
I am confident in this
4.2
understand how to represent organic molecules using empirical formulae, molecular
formulae, general formulae, structural formulae and displayed formulae
I know none of this
I know some of this
I am confident in this
4.3
know what is meant by the terms homologous series, functional group and isomerism
I know none of this
I know some of this
I am confident in this
4.4
understand how to name compounds relevant to this specification using the rules of
International Union of Pure and Applied Chemistry (IUPAC) nomenclature
students will be expected to name compounds containing up to six carbon atoms
I know none of this
I know some of this
I am confident in this
4.5
understand how to write the possible structural and displayed formulae of an organic
molecule given its molecular formula
I know none of this
I know some of this
I am confident in this
4.6
understand how to classify reactions of organic compounds as substitution, addition
and combustion
knowledge of reaction mechanisms is not required
I know none of this
I know some of this
I am confident in this
4.7
know that crude oil is a mixture of hydrocarbons
I know none of this
I know some of this
I am confident in this
4.8
describe how the industrial process of fractional distillation separates crude oil into
fractions
I know none of this
I know some of this
I am confident in this
4.9
know the names and uses of the main fractions obtained from crude oil:
refinery gases, gasoline, kerosene, diesel, fuel oil and bitumen
I know none of this
I know some of this
I am confident in this
4.10
know the trend in colour, boiling point and viscosity of the main fractions
I know none of this
I know some of this
I am confident in this
4.11
know that a fuel is a substance that, when burned, releases heat energy
I know none of this
I know some of this
I am confident in this
4.12
know the possible products of complete and incomplete combustion of hydrocarbons
with oxygen in the air
I know none of this
I know some of this
I am confident in this
4.13
understand why carbon monoxide is poisonous, in terms of its effect on the capacity
of blood to transport oxygen
references to haemoglobin are not required
I know none of this
I know some of this
I am confident in this
4.14
know that, in car engines, the temperature reached is high enough to allow nitrogen
and oxygen from air to react, forming oxides of nitrogen
I know none of this
I know some of this
I am confident in this
4.15
explain how the combustion of some impurities in hydrocarbon fuels results in the
formation of sulfur dioxide
I know none of this
I know some of this
I am confident in this
4.16
understand how sulfur dioxide and oxides of nitrogen contribute to acid rain
I know none of this
I know some of this
I am confident in this
4.17
describe how long-chain alkanes are converted to alkenes and shorter-chain alkanes
by catalytic cracking (using silica or alumina as the catalyst and a temperature in the
range of 600–700 ºC)
I know none of this
I know some of this
I am confident in this
4.18
explain why cracking is necessary, in terms of the balance between supply and
demand for different fractions
I know none of this
I know some of this
I am confident in this
4.19
know the general formula for alkanes
I know none of this
I know some of this
I am confident in this
4.20
explain why alkanes are classified as saturated hydrocarbons
I know none of this
I know some of this
I am confident in this
4.21
understand how to draw the structural and displayed formulae for alkanes with up to
five carbon atoms in the molecule, and to name the unbranched-chain isomers
I know none of this
I know some of this
I am confident in this
4.22
describe the reactions of alkanes with halogens in the presence of ultraviolet
radiation, limited to mono-substitution
knowledge of reaction mechanisms is not required
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4.23
know that alkenes contain the functional group >C=C<
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4.24
know the general formula for alkenes
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4.25
explain why alkenes are classified as unsaturated hydrocarbons
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4.26
understand how to draw the structural and displayed formulae for alkenes with up to
four carbon atoms in the molecule, and name the unbranched-chain isomers
knowledge of cis/trans or E/Z notation is not required
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4.27
describe the reactions of alkenes with bromine to produce dibromoalkanes
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4.28
describe how bromine water can be used to distinguish between an alkane and an
alkene
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4.44
know that an addition polymer is formed by joining up many small molecules called
monomers
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4.45
understand how to draw the repeat unit of an addition polymer, including
poly(ethene), poly(propene), poly(chloroethene) and (poly)tetrafluoroethene
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4.46
understand how to deduce the structure of a monomer from the repeat unit of an
addition polymer and vice versa
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4.47
explain problems in the disposal of addition polymers, including:
• their inertness and inability to biodegrade
• the production of toxic gases when they are burned.
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